Synthesis, structures, electrochemical studies and antioxidant activities of cis-dioxomolybdenum(VI) complexes of the new bisthiocarbohydrazones
By Yeliz Kaya and Ay?e Er
Published in Journal of Molecular Structure
2015
Abstract
Potentially pentadentate \ONSNO\ donor new Schiff bases were prepared by the condensation of thiocarbodihydrazide with 3,5-dibromosalicylaldehyde (H3L1), 3-bromo-5-chlorosalicy-laldehyde (H3L2) and 3,5-dichlorosalicylaldehyde (H3L3). The reactions between bis (acetylacetonato) dioxomolybdenum(VI) and Schiff bases in the presence of donor solvents yielded neutral cis-dioxomolybdenum(VI) complexes with the general formula [MoO2HL(D)] (HL