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Synergistic effects of fluoride and chloride on general corrosion behavior of {AISI} 316 stainless steel and pure titanium in {H2SO4} solutions

By Wang, Z. B.; Hu, H. X.; Zheng, Y. G.
Published in Corrosion Science 2018

Abstract

The general corrosion behavior of {AISI} 316 stainless steel (316 SS) and pure titanium (pure Ti) in {H2SO4} solutions containing fluoride (F?) and chloride (Cl?) ions was evaluated quantitatively using potentiodynamic polarization tests. The general corrosion resistance of these two materials to F? and Cl? is compared and explained by the proposed mechanisms based on {XPS} analyses. Furthermore, F? and Cl? are found to have synergistic effects on the general corrosion behavior of these two materials, which are attributed to the effects of F? and Cl? on the penetration of each other into the film.

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