Some may tell you that a Gamry Series G Potentiostat is noisy because it's installed inside a noisy computer. 

Here's why they're wrong.

 

The Bottom Line
Gamry’s specification for “Noise and Ripple” of the applied potential for the Series G 300 and Series G 750 is 20 µV(microVolts) rms (1 Hz – 10 kHz).  For the Reference 600 Potentiostat, the noise specification is less than 10 µV(microVolts) rms.  We guarantee this specification for our Potentiostats in any Windows-compatible computer in any laboratory in the world.  Compare this value to the noise specification for any other commercial potentiostat.  Our search found no instrument whose noise specification matched or exceeded Gamry’s!  

We're amazed that a few potentiostat manufacturers do not publish a noise specification. It's a very important specification.  You really shouldn't buy a potentiostat for which the noise level is not specified.  

Technical Details
In the lore of scientific instruments, a computer is considered to be electronically noisy.  If that is true, then it seems counter-intuitive to expect a potentiostat that is installed inside a computer to exhibit low noise.  How does Gamry do it? 

Is a computer noisy?  Yes, a computer has very high noise levels inside its cabinet.  A computer is a digital device, which generates both magnetic and electric fields as its internal signals switch.  These fields can couple noise into analog circuits.  However (and this is important) the noise in a computer occurs at very high frequencies, typically greater than 100 MHz.  These frequencies are far higher than the frequencies that are important to electrochemistry.  So, yes a computer is noisy, but it doesn't matter.

Grounding. The Gamry Potentiostat uses optical or transformer couplers to electrically isolate the analog potentiostat from the earth ground of the computer in which it is installed.  Large AC currents flowing through the computer’s ground would otherwise create noise in the potentiostat. 

Filters. The Gamry Series G Potentiostat contains three analog filters at 5 Hz, 1000 Hz, and 200 kHz.  The Reference 600 has four filters.  One of these filters is always active, discriminating against the computer’s high frequency noise. 

Shielding.  If you examine a Gamry Series G Potentiostat, you’ll see a big sheet of metal that completely covers the analog components of the Potentiostat.  This is a shield that protects the Potentiostat from electrostatic pickup of computer noise. 

What about the other guys? If Gamry’s noise spec is 20 µV rms, shouldn’t other manufacturers have an even lower noise spec?  After all, their potentiostat is not inside the computer!  The conclusion is simple...our engineers are better than their engineers!  

It turns out, by the way, that the greatest source of noise for a potentiostat that is connected to the power grid through a receptacle in the wall is the 50 Hz or 60 Hz signal from the mains.  AC power voltage presents two problems:  (1) its amplitude is very large, either 110 or 220 volts, and (2) it is at a frequency that is of interest to the electrochemist, so filtering is difficult.  Noise may be a real problem at the mains frequency or at some harmonic, e.g., 120 Hz or 180 Hz.   

Since we’re on the subject, what does “Noise and Ripple” really mean? For a Gamry Potentiostat, the noise level that will be observed on the applied potential is less than 20 µV rms (root mean square).  To convert rms to peak-to-peak, multiply by 1.414 (square root of 2) to convert to a peak signal, then multiply by 2 to convert to peak-to-peak.  
 
Noise in the applied voltage often shows up in the current measurement.  A 1 cm2 electrode with 40 µF of capacitance has an impedance of about 30 ohms at 120 Hz.  A potentiostat with 50 µV of noise at 120 Hz connected to this electrode will generate a noise current greater than 4 µA peak-to-peak.   It is impossible to measure a 10 µA current signal that is contaminated with this much noise!  

 

Make a smart decision. If someone tells you something negative about Gamry, they may not have your best interests in mind.  Contact us and ask for our comments.

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Last revised on Wednesday, January 03, 2007